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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Refinery Sources
Catalytic Cracking
Thermal Operations
Coproduct from Ethylene Production
Ethylene Oligomerization
alpha-Olefin Production
Ethylene Dimerization
Dehydrogenation of n-Butane and Isobutane
Dehydration of tert-Butyl Alcohol to Isobutylene
Cracking of Methyl tert-Butyl Ether
Hydrogenation of C4 Hydrocarbons
Isomerization of n-Butenes to Isobutylene
Uses
Fuel Uses
Dimersol
Gasoline Alkylate
MTBE (Methyl tert-Butyl Ether) and ETBE (Ethyl tert-Butyl Ether)
Polymer Gasoline
Direct Blending
Other Fuel Uses
Chemical Uses
Chemical Uses for n-Butenes
Butadiene
Butene-1
Polyethylene copolymer
Polybutene-1
Valeraldehyde
1,2-Butylene oxide
Other butene-1 uses
Butene-2
Propylene
Octenes
sec-Butyl Alcohol
Polygas and Dimersol Chemicals
Chemical Uses for Isobutylene
High-Purity Isobutylene Derivatives
Butyl rubber
Methyl methacrylate (MMA)
Polyisobutylenes
Substituted phenols
Other high-purity isobutylene uses
Polybutenes
Chemical Uses for Diisobutylene and Triisobutylene
Supply and Demand by Region
United States
Producing Companies
Refinery Butylenes
Ethylene Coproduct
High-Purity Butylenes
Production
Refinery Operations
Ethylene Coproduct
Production of Isomers
Consumption
Fuel Uses
Gasoline alkylate
MTBE
ETBE
Polymer gasoline and dimersol
Other fuel uses
n-Butenes for Chemical Consumption
Butene-1
Butene-2
sec-Butyl alcohol
Polygas and dimersol chemicals
Butadiene
Isobutylene for Chemical Consumption
Polybutenes
High-purity isobutylene derivatives
Diisobutylene and triisobutylene
Price
Gasoline and Other Alternative Fuel Values
High-Purity Isobutylene Values
Trade
Canada
Producing Companies
Refinery Butylenes
Ethylene Coproduct
Butane Dehydrogenation
Production
Consumption
Fuel Uses
Alkylation
MTBE and isooctane
Chemical Uses
Price
Trade
Mexico
Producing Companies
Refinery Butylenes
Ethylene Coproduct
Production
Consumption
Fuel Uses
Alkylation
MTBE
Chemical Uses
Trade
Central and South America
Producing Companies
Refinery Butylenes
Ethylene Coproduct
Butane Dehydrogenation
Production
Consumption
Fuel Uses
Alkylation
MTBE
Chemical Uses
Trade
Western Europe
Producing Companies
Refinery Butylenes
Ethylene Coproduct
High-Purity Butylenes
Production
Consumption
Fuel Uses
Alkylation
MTBE
Polygas blending
Chemical Uses
sec-Butyl alcohol
Butene-1
High-purity isobutylene
Price
Trade
Central and Eastern Europe
Africa
Middle East
Japan
Producing Companies
Refinery Butylenes
Ethylene Coproduct
Producers of Butylenes for Chemicals
Production
Consumption
Fuel Uses
Alkylation
Polymer gasoline and dimersol
MTBE
Chemical Uses
Mixed butylenes
n-Butenes
Isobutylenes
Price
Trade
Other Regions
Other Asia
Oceania
   
  Butylenes
   
  Sean Davis and Masahiro Yoneyama
  Published November 2008
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  Abstract
   
 

This report provides an assessment of the supply/demand situation for butylenes in 2007 and market projections for 2012. The focus of the study is the worldwide butylenes market, an evaluation of the worldwide supply of butylenes, and the consumption of butylenes for producing chemicals and gasoline blending components where data are available.

Butylenes are four-carbon mono-olefins that find use in fuel and chemical applications. Fuel markets account for about 90% of the world production of butylenes. The major fuel application is in the manufacture of gasoline blending components, such as gasoline alkylate, polymer gasoline and dimersol. Isobutylene serves as a raw material for the oxygenates, methyl tert-butyl ether (MTBE) and ethyl tert-butyl ether (ETBE), as well as for iso-octane. Butylenes may also be blended directly into gasoline for volatility control. They are also marketed with propane and butanes as liquefied petroleum gas (LPG).

At about 10% of the total worldwide market for butylenes, the size of the chemical market pales in comparison to that of the fuel market. n-Butenes are used as the precursor for sec-butyl alcohol, butadiene, butene-1 and other smaller applications. In the United States, Western Europe and Japan the chemical market for n-butenes is growing slowly; however, in developing regions, demand for butene-1 as a polyethylene comonomer and sec-butyl alcohol for MEK remain high. Environmental regulations have slowed the growth of chemical markets for isobutylene in the United States and Japan with the gradual cessation of MTBE use in reformulated gasoline. Japan ceased MTBE production in 2001, while the United States will most likely end by 2013. Other isobutylene derivatives such as butyl rubber and polybutenes in these regions are mature markets and will see only small growth. Stronger isobutylene demand in Other Asia, Central and South America, and Central and Eastern Europe is forecast through 2012.

The following pie charts show world consumption of butylenes for fuel uses and for chemical uses.

In the United States, chemical demand for n-butenes is expected to remain relatively stagnant during 2007–2012 despite moderate growth for butene-1. A projected decline in sec-butyl alcohol production and the mature nature of the market for plasticizer alcohols produced from heptenes and octenes will lower overall demand. In addition, the production of propylene via metathesis, currently operating near capacity, is expected to decline with the decline in domestic demand for polypropylene. Isobutylene consumption growth for all chemical derivatives (excluding MTBE) is expected to grow only slowly; consumption for MTBE continues to decline. Isobutylene consumption for MTBE declined significantly during 2000–2007, and is expected to continue to do so during the 2007–2012 period, potentially eliminating all MTBE production throughout the United States.

Western European consumption of n-butenes for chemical use will grow well, while isobutylene use (excluding MTBE) will decrease slowly during 2007–2012. The use of isobutylene for MTBE/ETBE production will remain level. The use of isobutylene for ETBE is expected to grow faster and offset declines in MTBE demand.

Japan’s chemical markets for n-butenes will grow strongly and for isobutylene very slowly during 2007–2012. Since August 2004, n-butene demand for propylene production via butylene metathesis quadrupled to 2007, but will slow over the forecast period. MTBE production in Japan for gasoline began in 1992 and peaked in 1999. Refiners discontinued production of MTBE and mixing MTBE in gasoline in mid-2001 after MTBE was found in groundwater. Future isobutylene growth will come from butyl rubber, methyl methacrylate and diisobutylene demand.

 
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