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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Natural Cresols
Synthetic Cresols and Xylenols
Alkali Fusion of Toluenesulfonates
Alkali Hydrolysis of Chlorotoluene
Cymene Hydroperoxide Cleavage
Methylation of Phenolics
Demethanization of Isophorone
Separation of (m,p)-Cresol Mixtures
Environmental Issues
Supply and Demand by Region
United States
Producing Companies
Production and Sales
Consumption
o-Cresol
m-Cresol
p-Cresol
(m,p)-Cresols
Xylenols and Trimethylphenols
Cresylic Acids
Price
Trade
Imports
Exports
Canada
Salient Statistics
Consumption
Trade
Mexico
Salient Statistics
Consumption
Trade
Central and South America
Producing Companies
Salient Statistics
Consumption
Western Europe
Producing Companies
Production
Consumption
o-Cresol
Herbicides
Epoxy-o-cresol novolac resins
Antioxidants
Other
m-Cresol
Antioxidants
Thymol/menthol
Agrochemicals
p-Cresol
Antioxidants
p-Anisaldehyde
Other
(m,p)-Cresols
Xylenols
2,3-Xylenol
2,4-Xylenol
2,6-Xylenol
3,5-Xylenol
Xylenol mixtures
Cresylic Acids
Price
Trade
Imports
Exports
Central and Eastern Europe
Producing Companies
Salient Statistics
Consumption
Japan
Producing Companies
Production
Consumption
o-Cresol
m-Cresol
p-Cresol
(m,p)-Cresols
2,6-Xylenol
Other Xylenols
Cresylic Acids
Price
Trade
China
Producing Companies
Production
Consumption
Price
Trade
Other Asia
Producing Companies
Salient Statistics
Cresols and Cresylic Acids
Xylenols
Trade
India
Republic of Korea
Taiwan
Rest of the world
Producing Companies
Salient Statistics
Consumption
Trade
   
  Cresols, Xylenols and Cresylic Acid
   
  Emanuel V. Ormonde and He Xiaoxiong and Kazuteru Yokose
  Published November 2008
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  Abstract
   
 

Cresols (o-, m- and p-), xylenols and cresylic acids are phenolic compounds or mixtures used as raw materials for a variety of synthetic applications, polymer intermediates and also as solvents. Cresols and xylenols are obtained from a variety of sources. Generally, the two main avenues for obtaining cresols and/or xylenols are from natural sources (coal tars, coal gasification extracts) or synthetic processes. Synthetic cresols and xylenols are produced by a variety of processes. Production of synthetic cresols and xylenols from toluene is considered the preferred route.

Cresylic acids are basically a mixture of cresols. These acids are usually obtained by the processing of coal tars, coal gasification or petroleum extracts. The availability of coal tars and petroleum caustic extracts has been reduced because of changes in technology, causing many isolators of cresylics to terminate their operations. Cresylic acids are used mainly as a feedstock for the isolation of cresols, xylenols and their mixtures, as well as in direct use as a solvent for wire enamels.

The following pie chart shows world consumption of cresols, xylenols and cresylic acids:

In 2007, world consumption of cresols, xylenols and cresylic acids was about 5% higher than in 2004. The major world consumers of cresols, xylenols and cresylic acids are the United States, Western Europe, China and Japan, representing roughly 87% of the 2007 world total. Moreover, China overtook Japan (based on total quantity consumed) to become the third-largest consumer of cresols, xylenols and cresylic acids by 2007. Demand for cresols, xylenols and cresylic acids is expected to grow at 6–7% per year in China during 2007–2012.

 
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