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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Ethylene Oligomerization
Chevron Phillips Chemicals' Ethylene Oligomerization (Ziegler Process)
INEOS' Ethylene Oligomerization (Modified Ziegler Process)
Shell's Ethylene Oligomerization (Shell Higher Olefins Process - SHOP)
Idemitsu's Ethylene Oligomerization Process
Vista's Alfene@ Process
Exxon's Ethylene Oligomerization Process
DuPont's VersipoL(TM) Process
Other alpha-Olefin Synthesis Routes
Sasol's Purification Process
Paraffin Wax Cracking
Dehydration of Alcohols
Isomerization of Internal Olefins
Supply and Demand by Region
North America
Producing Companies
Production
Consumption
Polyethylene (PE) Comonomer
Linear low-density polyethylene (LLDPE) resins
High-density polyethylene (HDPE) resins
Elastomers and plastomers
Alcohols
Detergent alcohols
Plasticizer alcohols
Polyalphaolefins
Oil Field Drilling Fluids
Other Lubricant Additives
Alkyldimethylamines and Dialkylmethylamines
Synthetic Fatty Acids (C7-C9)
Alkenylsuccinic Anhydrides
alpha-Olefin Sulfonates
Linear Alkylbenzene
Linear Mercaptans
Aluminum Alkyls
Chlorinated Olefins
Alkyldiphenylether Disulfonates
Other
Price
Trade
Western Europe
Producing Companies
Salient Statistics
Consumption
Polyethylene
Polyalphaolefins
Oxo Alcohols
Detergent oxo alcohols
Plasticizer alcohols
Lube Oil Additives
alpha-Olefin Sulfonates
Linear Alkylbenzene
Other
Linear mercaptans
Alkenylsuccinic anhydride
Price
Trade
Central and Eastern Europe
South Africa
Middle East
Japan
Producing Companies
Salient Statistics
Consumption
HDPE/LLDPE Comonomers
Oxo Alcohols
Plasticizer alcohols
Detergent alcohols
alpha-Olefin Sulfonates
Other
Price
Trade
Other Asia
Appendix I
   
  Linear alpha-Olefins
   
  Elvira Greiner and Kazuaki Nakamura
  Published September 2007
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  Abstract
   
  This report covers supply/demand for linear alpha-olefins (LAOs) with carbon chain lengths of four (butene-1) and higher that are produced in facilities that generate an entire range of LAOs. Most of the current commercial LAO plants produce even-numbered alpha-olefins based on ethylene oligomerization. The exceptions are the coal-based synthetic fuel plant of Sasol Chemical Industries in South Africa, which currently produces only hexene-1 and octene-1; Q-Chem, which produces hexene-1 from ethylene; and Dow, which produces octene from butadiene in Tarragona, Spain. Butene-1, which is produced from refinery and steam cracker C4 hydrocarbon streams, is not included in this discussion.

World linear alpha-olefin capacity (excluding butene-1 from refinery streams) amounted to over 3.0 million metric tons by year-end 2006. As of mid-2007 there were ten producers of alpha-olefins operating twelve plants internationally. As shown in the following pie chart, four producers account for about 86% of world capacity:

The largest uses for linear alpha-olefins are as comonomers for polyethylene production, for the production of alcohols (used largely in detergents and plasticizers) and for making polyalphaolefins (used in synthetic lubricants).

The use of linear alpha-olefins in the production of polyethylene, for polyalphaolefins and for use in oil field drilling applications will be the fastest growing segments in North America. Globally, comonomer-grade LAO consumption will also be the fastest growing application, particularly LAO consumption for the production of linear low-density polyethylene resins.

 
Company Information
 

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