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Table of Contents
 
Summary
United States
Europe, africa and middle east
Japan
Introduction
Organotins
Description and Properties
Nonbiocidal Organotins - RSnX3 and R2SnX2
Description
Mechanism of PVC Stabilization with Mono- and Dialkyltins
Biocidal Organotins - R3SnX
Manufacturing Processes
Nonbiocidal Organotins
Biocidal Organotins
Environmental Issues
Supply and Demand by Region
United States
Producing Companies
Consumption
Nonbiocidal organotins
Biocidal organotins
Price
Trade
Canada
Western Europe
Producing Companies
Corporate activities
Associations and interest groups
Rules and Regulations
Salient Statistics
Consumption
PVC
Catalysts
Glass coatings
Biocides
Price
Trade
Central and Eastern Europe
Africa
Middle East
Japan
Producing Companies
Production
Consumption
Price
Trade
Other Asia
Organoaluminums
Description and Properties
Manufacturing Processes
Aluminum Alkyls and Hydrides
Aluminum Halides and Sesquihalides
Environmental Issues
Supply and Demand by Region
United States
Producing Companies
Consumption
Catalysts for polymer synthesis
Catalysts for other syntheses
Price
Trade
Canada
Western Europe
Producing Companies
Salient Statistics
Consumption
Price
Trade
Central and Eastern Europe
Africa
Middle East
Japan
Producing Companies
Salient Statistics
Production
Consumption
Price
Trade
Imports
Exports
Other Asia
Producing Companies
Consumption
Organomagnesiums and Organolithiums
Description and Properties
Organomagnesium Compounds
Organolithium Compounds
Manufacturing Processes
Organomagnesium Compounds
Organolithium Compounds
Environmental Issues
Supply and Demand by Region
United States
Producing Companies
Consumption
Organomagnesium compounds
Organolithium compounds
Price
Trade
Western Europe
Producing Companies
Organomagnesium compounds
Organolithium compounds
Salient Statistics
Organomagnesium compounds
Organolithium compounds
Price
Trade
Central and Eastern Europe
Africa
Middle East
Japan
Producing Companies
Organomagnesium compounds
Organolithium compounds
Consumption
Organomagnesium compounds
Organolithium compounds
Price
Trade
Other Asia
Organozincs
Supply and Demand by Region
United States
Producing Companies
Consumption
Trade
Western Europe
Producing Companies
Consumption
Price
Trade
Central and Eastern Europe
Africa
Middle East
Japan
   
  Organometallics
   
  Bala Suresh and Hossein Janshekar and Masahiro Yoneyama
  Published October 2008
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  Abstract
   
 

The main product categories covered in this report are organoaluminums, organotins, organolithiums and organomagnesiums.

Organoaluminums are used primarily as catalysts for the synthesis of polymers, including polypropylene, polyethylene and several elastomers. Use as a catalyst for other syntheses includes olefin oligomerization and the Dimersol process for gasoline production. Furthermore, organoaluminums are used in the synthesis of other organometallics and as reducing agents.

Organotins are split by application into two groups—biocidal and nonbiocidal. Nonbiocidal organotins are used largely as additives for polyvinyl chloride (PVC), but also in catalysis of several products, including rigid polyurethanes and silicones. Biocidal organotins are used in agriculture as fungicides and miticides, and as preservatives/antifoulants on wood surfaces, in closed-circuit cooling towers and in marine paints.

Organolithiums are used as catalysts for polybutadiene elastomer production and in the synthesis of pharmaceuticals. Organomagnesiums are used as catalysts for polyolefin production and in the synthesis of pharmaceutical and fine chemicals.

The following pie chart shows world consumption of organometallics by type:

The overall business environment for organometallics is characterized in part by the following:

  • Greater regulations and restrictions (e.g., tributyltins in markets such as biocides/paint and PVC stabilizers). Because of stricter environmental demands, organotin antifoulants have been phased out and replaced by copper-based alternatives.
  • Rising raw material (metals) costs affecting development of markets for some organometallics in certain applications (e.g., organotin stabilizers).
  • Steadily falling demand in some regions such as Western Europe for organometallics (e.g., tin derivatives) in applications such as agriculture, rigid polyvinyl chloride.
 
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