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Table of Contents
 
Summary
Introduction
Manufacturing Processes
Synthetic Production
Natural Product Isolation
Environmental Issues
Supply and Demand by Region
United States
Producing Companies
Salient Statistics
Production
Consumption
Pyridine
2-Chloropyridine
Piperidine
Agricultural chemicals
Solvent and other
alpha-Picoline
Agricultural chemicals
2-Vinylpyridine
Animal feed additives and other
beta-Picoline
Agricultural chemicals
Niacinamide
3-Cyanopyridine (noncaptive)
Other
gamma-Picoline
Price
Trade
Imports
Exports
Canada
Salient Statistics
Trade
Mexico
Salient Statistics
Trade
Central and South America
Salient Statistics
Trade
Western Europe
Producing Companies
Synthetic Producers
DSM Fine Chemicals BV
Lonza AG
Tar-Based Producers
RUETGERS Chemicals GmbH
Schenectady Europe Ltd.
Production
Consumption
Pyridine
Agricultural chemicals
Other
alpha-Picoline
beta-Picoline
gamma-Picoline
2-Methyl-5-Ethylpyridine
Lutidines and Collidines
Price
Trade
Central and Eastern Europe
Producing Companies
Production
Consumption
Trade
Japan
Producing Companies
Production
Consumption
Pyridine
alpha-Picoline
beta-Picoline
gamma-Picoline
Price
Trade
Imports
Exports
Other Asia
Producing Companies
Salient Statistics
China
India
Indonesia
Republic of Korea
Taiwan
Consumption
Price
Trade
China
India
Taiwan
   
  Pyridines
   
  Sebastian Bizzari and Thomas Kaelin and Akihiro Kishi
  Published December 2007
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  Abstract
   
 

Pyridine and beta-picoline accounted for 72% of world consumption of pyridines in 2007. Agricultural chemicals, mainly the nonselective contact herbicide paraquat, account for most consumption of pyridine; however, demand for piperidine and 2-chloropyridine is growing well in some regions, albeit from a small base. beta-Picoline, which is used to produce niacinamide/niacin (vitamin B3), is forecast to grow as a result of strong demand for niacinamide/niacin in developing regions such as Asia, Africa, and Central and South America for use in animal feed (mainly poultry and dairy cattle). 2-Methyl-5-ethylpyridine (MEP) is used nearly entirely to produce niacin. The largest market for alpha-picoline is 2-vinylpyridine (2-VP); most 2-VP is used as a component of styrene-butadiene-2-vinylpyridine terpolymer latexes (SBV latexes), which are used as tire cord adhesives and in other adhesives for bonding textiles to elastomers.

The following pie chart shows world consumption of pyridines:

Consumption of pyridine for paraquat declined substantially in the United States in late 2006, a result of the termination of paraquat production at Bayport, Texas by Syngenta Crop Protection. Additionally, a ban on paraquat use in the European Union has dampened prospects for future consumption growth for pyridine in Europe; future consumption of pyridine for paraquat in Europe will be largely dependent on export demand. China will account for most growth in demand of pyridines for paraquat and other agricultural chemicals such as chlorpyrifos, which is derived from beta-picoline.

Growth in demand for pyridines varies by product and region. Growth in the Americas and Europe is forecast to be moderate; of the large-volume applications, niacinamide/niacin has the best prospects. Other growth markets in the United States include 2-chloropyridine (a precursor in the production of antimicrobial pyrithione salts) and piperidine (largely for exports). Significant growth is expected in China, largely for increased production of paraquat and other agricultural chemicals and niacinamide/niacin. Asian consumption of paraquat is expected to grow quickly, largely as a result of increased commercial agricultural activity and increased acreage of plants for renewable biofuels, such as palm oil trees.

 
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