Process Economics Program Report 1F
Published: Feb-2002
Aliphatic and cycloaliphatic diisocyanates (functional
groups -N=C=O) are major building blocks in the manufacture of polyurethane
products, which are formed by the controlled polyaddition of the diisocyanates
with either polyether or polyester polyol coreactants. These diisocyanates are
consumed primarily in non-yellowing, high-performance industrial and automotive
polyurethane coatings applications.
Industrial scale production of aliphatic and cycloaliphatic
diisocyanates has previously been accomplished by the phosgenation of the diamines.
However, in recent years, there has been no lack of attempts to prepare these
diisocyanates by phosgene-free processes commercially mainly because of phosgene’s
corrosivity, high toxicity and high chlorine content. In the mid-1990s, Degussa
(previously Creanova or Huls) started-up a 20 million lb/yr IPDI unit in Theodore,
Alabama, employing its proprietary phosgene-free urea-based technology; BASF
was also believed to have brought on stream a 20 million lb/yr HDI/IPDI swing
plant in Germany using a similar patented phosgene-free process.
This report, our sixth on the topic of isocyanates since
1967, presents a comprehensive assessment of the status of the aliphatic and
cycloaliphatic diisocyanates industry, primarily HDI and IPDI. It provides a
review of current patents and recent business/technology developments, and evaluates
major commercial processes. This report also presents two conceptual process
designs and economic evaluations for the production of hexamethylene diisocyanate
(HDI) and isophorone diisocyanate (IPDI) using non-phosgene urea-based technologies
developed by BASF and Degussa. Also presented are updates of the techno-economics
in the production of similar scale HDI and IPDI via conventional phosgenation
processes. Results of our economic comparison indicate that the phosgene-free
urea-based processes are generally more expensive in total fixed capital than
their conventional phosgene-based counterparts. Although raw material costs
for the non-phosgenation processes are lower, the higher cost of utilities and
capital related fixed costs nonetheless result in product values that are 3-7%
higher than those obtained via conventional phosgene processes.
In addition, other aliphatic and cycloaliphatic diisocyanates,
such as H12MDI (hydrogenated MDI), are also introduced and discussed briefly
in the industry status of this report. Overall, this report encompasses the
latest technology and process economics, and it provides a basis for insight
into technology trends, and possible enhancement in safety and environmental
standards with the new phosgene-free routes in the preparation of HDI and IPDI.
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